Correlation between the 1:2 atomic order and microwave dielectric loss in the off-stoichiometric Ba(Zn1/3Ta2/3)O3
2018
Abstract We report close correlation between the 1:2 atomic order and microwave dielectric loss in the off-stoichiometric Ba(Zn 1/3 Ta 2/3 )O 3 (BZT). Small off-stoichiometric deviations have a large effect on the ordering and Q × f values. The Ba 4 Ta 2 O 9 -BZT-‘Zn 4 Ta 2 O 9 ’ pseudo tie line separating the Ta-rich and Ta-poor regions also demarcates the 1:2 ordered and disordered BZT. The low-loss off-stoichiometric BZT ceramics are located in the 1:2 ordered region of the BaO-ZnO-Ta 2 O 5 phase diagram. Without exception the disordered BZT ceramics show high dielectric loss. Stoichiometric BZT with 1:2 atomic order shows Q × f = 113 THz. The off-stoichiometric 1:2 ordered BZT ceramics with the highest Q × f > 200 THz are located in the ZnO-deficient part of the ternary phase diagram.
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