A Au(I)-Precatalyst with a Cyclopropenium Counterion: An Unusual Ion Pair.
2016
The synthesis and X-ray crystal structure of a novel Au(I)-precatalyst applied to intermolecular alkyne hydroamination is reported. Density functional theory (DFT) calculations revealed the cyclopropenium counterion of this Au(I)-precatalyst imparts stability through H-bonding and other noncovalent interactions.
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