Esters and thioesters thiazole-4-carboxylic acid as crop protection agents

2009 
Compounds of formula (I) wherein the symbols have the following meanings: R1 and R3 are independently H, C1-C4 alkyl, C2-C4, C2-C4 alkynyl, C3-C6 alkyl, halocycloalkyl C3-C6, C1-C4 alkoxy, C1-C4 haloalkyl, C1-C4 haloalkoxy, halogen, hydroxy, cyano or phenyl, R2 is H, phenyl, C1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkynyl, C3-C6 alkyl, halocycloalkyl C3-C6, C1-C4 alkoxy, C1-C4 alkyl, C1-C4 haloalkoxy, formyl, CR8> = NOR9, halogen, hydroxy, cyano or NR10R11, or R1 and R2 or R2 and R3 form together with the carbon atoms to which are attached a cycle of 5 to 7 substituted or unsubstituted, partially saturated or unsaturated membered ring which can contain up additional selected dosheteroatomos from N, O and S, no two oxygen atoms are adjacent, the substituents being selected possible independently from C1-C4 alkyl, hydroxy, oxo or 15 halogen, R4 and R5 are independientement and each other H, C1-C4 alkyl, C3-C6 or C1-C4 haloalkyl, or R4 and R5 form together with the carbon atom to which they are attached, a saturated cycle of 3 to 6 membered can contain up to two selected from N and O, no two oxygen atoms, Y1, Y2 represents oxygen, Y 3 represents sulfur or oxygen, X represents a direct bond or a carbon chain C1 to C3 substituted or unsubstituted are adjacent heteroatoms in quelos atoms carbon carry as substituents independently H, methyl or oxo, W represents a carbon chain C1 to C3 substituted or unsubstituted, in which the carbon atoms bearing as substituents independently H, methyl or oxo, R6 represents H, C1-C4 alkyl, C1-C4 haloalkyl, CONR10R11, (alkoxy C1-C4) alkoxycarbonyl, COOH, NR10R11, halogen or cyano, G is (C (R12) 2) m, with m> = 0 to 6, R7 represents C5-C10 alkyl, C2-C16 alkenyl, C2-C16 alkynyl, C3-C15 cycloalkyl, cycloalkenyl C5- C15 heterocyclyl C3-C15, aryl, hetaryl or Si (C1-C4) 3 substituted or unsubstituted, the substituents being selected possible independently from the following list: halogen, cyano, nitro, nitroso, C1-C4 alkyl, C1-C4 haloalkyl, aryl C1-C3, arilhaloalquilo C1-C3 alkyl, hydroxy, oxo, C1-C4 alkyl, O (alkyl C1-C6) mO-C1-C6 alkyl, O-C3-C6 cycloalkyl, O-phenyl, C1-C4 haloalkoxy, SH, thioalkyl C1-C4, thiohaloalkyl C1-C4, S-phenyl, SO2-C1-C6 alkyl, SO2-C1-C6 alkyl, SO-C1-C6 alkyl, SO-C1-C6, CO2H , (C1-C4 alkyl) carbonyl, (C1-C4-haloalkyl) carbonyl, formyl, CR8> = NOR9, CONR10R11, (C1-C4 alkoxy) carbonyl, COOH, NR10R11, cyclopropylamino, CH2COCH3, (CH2) mO- C1-C6 alkyl, CH2OH, CH2SMe, (CH2) 2SMe, C3-C6, 1-metoxiciclopropilo, 1-chlorocyclopropyl, cyclohexylmethyl, C2-C6 alkenyl, C2-C6 alkynyl, If alkyl (C1-C4) 3, phenyl or benzyl, or two adjacent substituents form a dioxolane ring or dioxane sustituid or, optionally, with metiloo halogen, R8, R9, R10, R11 are independently H, C1-C3 alkyl or cyclopropyl, or R10 alkyl and R11 form together with the nitrogen atom to which they are attached, a saturated cycle of 3 6 miembrosque can contain up to one additional heteroatom selected from N or O, R12 is identical or different and independently H, chlorine, fluorine, C1-C3, C1-C3, C3-C6 cycloalkyl or trifluoromethyl, or two or four R12 on two adjacent carbon atoms, respectively, represent direct bonds, and salts whose component agrochemical activity is a substance according to formula (1).
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