Concentration-Dependent Impact of Alkali Li MetalDoped Mesoporous TiO 2 Electron Transport Layer on the Performanceof CH 3 NH 3 PbI 3 Perovskite Solar Cells

TiO2 is most commonly employed as an electron transport layer (ETL) in mesoscopic n–i–p perovskite solar cells (PSCs). However, the low electron mobility, low electrical conductivity, and high electronic trap states of TiO2 may have negative impacts on further enhancement of PSC performance. Metal doping is an efficient way to improve the electronic properties of TiO2 films. In this work, we investigate the concentration-dependent impact of alkali lithium metal doping of the mesoporous TiO2 ETL on the performance of mesoscopic CH3NH3PbI3 PSCs. It was found that Li doping results in remarkable improvement in electrical conductivity and electron mobility and reduces the number of electronic trap states arising due to the oxygen vacancies within TiO2 lattice. Such enhancements led to an enhanced charge extraction and transport and reduced charge recombination rate at the perovskite/mesoporous TiO2 interface as revealed by steady-state photoluminescence (PL) and time-resolved PL (TRPL) spectra, and resulted i...