catena-Poly[[[[μ-bis(diphenylphosphino)amine-κ2P:P′]bis[acetonitrilecopper(I)]]-μ-(1,2-dicyanoethylene-1,2-dithiolato)-[(1,2-dicyanoethylene-1,2-dithiolato)molybdenate(IV)]-μ-1,2-dicyanoethylene-1,2-dithiolato] acetonitrile disolvate]
2007
Reaction of (Bu4N)2[Mo(mnt)3] (mnt = cis-1,2-dicyanoethylene-1,2-dithiolate) with [Cu2(dppa)2(MeCN)4](ClO4)2 [dppa = bis(diphenylphosphino)amine] yields the polymeric heterometallic title compound, {[Cu2Mo(mnt)3(μ-dppa)2(MeCN)2]·2CH3CN}n or {[Cu2Mo(C4N2S2)3(C24H21NP2)2(C2H3N)2]·2C2H3N}. The compound exhibits a polymeric zigzag structure formed from [Mo(mnt)3]2− and [Cu2(dppa)2(MeCN)2]2+ units linked by coordination of the CN groups of the mnt ligands to the CuI centres.
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