From Highly Enantioselective Catalytic Reaction of 1,3-Diynes with Aldehydes to Facile Asymmetric Synthesis of Polycyclic Compounds.

Mark Turlington,Yuhao Du,Samuel G. Ostrum,Vishaka Santosh,Kathryne Wren,Tony Lin,Michal Sabat,Lin Pu

From Highly Enantioselective Catalytic Reaction of 1,3-Diynes with Aldehydes to Facile Asymmetric Synthesis of Polycyclic Compounds.

2011

Mark Turlington
Yuhao Du
Samuel G. Ostrum
Vishaka Santosh
Kathryne Wren
Tony Lin
Michal Sabat
Lin Pu

Highly enantioselective addition of various 1,3-diynes towards aromatic and aliphatic aldehydes is smoothly achieved in the system Et2Zn—(S)-BINOL—Ti(O-iPr)4.

Keywords:

Enantioselective synthesis
Organic chemistry
Catalysis
Chemistry

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