Lanthanide(III) Complexes of 4,10‐Bis(phosphonomethyl)‐1,4,7,10‐tetraazacyclododecane‐1,7‐diacetic acid (trans‐H6do2a2p) in Solution and in the Solid State: Structural Studies Along the Series
2010
Complexes trans-H6do2a2p (H6L)with transition metal and
lanthanide(III) ions were investigated. Values of stability
constants complexes are intermediate in the ligand series as a
consequence of this ligand basicity. The solid-state structures
of the ligand and nine lanthanide(III) complexes were
determined by X-ray diffraction. The formation kinetics and the
acid-assisted dissociation of several Ln(III)-H6L complexes
were investigated. According to the 1H NMR pseudo-contact
shifts for the Ce–Eu and Tb–Yb series, the solution structures
of the complexes reflect the structures of the [Ce(HL)(H2O)]2–
and [Yb(HL)]2– anions, respectively, found in the solid state.
However, these solution NMR studies showed that there is no
unambiguous relation between 31P/1H lanthanide induced shift
(LIS) values and coordination of water in the complexes.
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