Ruthenium-Catalyzed Orthoselective Aromatic C—H Silylation: Acceptorless Dehydrogenative Coupling of Hydrosilanes.

Toru Sakurai,Yusuke Matsuoka,Tsurugi Hanataka,Naoaki Fukuyama,Takeshi Namikoshi,Shinji Watanabe,Miki Murata

Ruthenium-Catalyzed Orthoselective Aromatic C—H Silylation: Acceptorless Dehydrogenative Coupling of Hydrosilanes.

2012

Toru Sakurai
Yusuke Matsuoka
Tsurugi Hanataka
Naoaki Fukuyama
Takeshi Namikoshi
Shinji Watanabe
Miki Murata

The intermolecular dehydrogenative coupling of trisiloxane (II) with aromatic compounds such as arylimines (I) and aryloxazolines (VI) in the presence of a Ru-catalyst affords the corresponding ortho-silylated products in good yields.

Keywords:

Ruthenium
Silylation
Catalysis
Coupling
Chemistry
Intermolecular force
Organic chemistry

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