Oleic acid induced tailored morphological features and structural defects in CuO for multifunctional applications

Synergistically tuned noble metals and intentionally formed complex heterostructured nanomaterials can enhance the required application effectiveness but at the cost of tedious synthesis routes, expensive chemicals, and sophisticated instruments. To overcome such demerits, herein, we report on the oleic acid-mediated convenient co-precipitation route using water-hexane as a biphasic solvent for CuO synthesis in the form of nano feathers (CuO-NF), solid/hollow hexagonal thin sheets (CuO-HS), and mega sheets (CuO-MS) at room temperature. Exotic CuO nanoarchitectures achieved were tested and compared with control samples (CuO-IS) for CO2 sensing, natural sunlight induced dye degradation, and catalytic CO2 reduction. Among the various CuO nanostructures synthesized, CuO-HS depicted higher oxygen deficiency, electronic conductivity, and visible light absorption. Most of the solid/hollow hexagonal thin sheets depicted edge length in the 50-350 nm range with an observed thickness as low as 5 nm. The CuO-HS microsensor demonstrated ultrasensitivity (Rg/Ra= ~85), dominant selectivity (>6 gases), repeatability (98.7%), CoV (1.3%), and LoD (4.3 ppm) at 32oC towards CO2 in 20-5,000 ppm. The role of structural defects during sensing was confirmed from operando UV-DRS & PL. Rapid dye degradation in natural sunlight was shown by CuO-HS, primarily attributed to the lower charge reunification. Additionally, CuO-HS facilitated methanol formation within 3 h at a rate of 53 and 18 μmol.g-1 in presence of artificial solar and natural sunlight, respectively. Dye degradation and CO2 photoreduction pathways were probed using HPLC and GC-MS, respectively.