Synthesis, structural characterization of benzimidazole-functionalized Ni(II) and Hg(II) N-heterocyclic carbene complexes and their applications as efficient catalysts for Friedel–Crafts alkylations
2011
Abstract [Ni(L 1 ) 2 ](PF 6 ) 2 ( 3a , L 1 = 3-(1-ethyl-1 H -benzimidazol-2-yl)methyl)-1-((6-methylpyridin-2-yl)methyl)imidazolyl-idene), [Ni(L 2 ) 2 (CH 3 CN)](PF 6 ) 2 ( 3b , L 2 = 3-(1-ethyl-1 H -benzimidazol-2-yl)methyl)-1-((6-methylpyridin-2-yl)-methyl)benzimidazolylidene), and [Hg(L 1 ) 2 (CH 3 CN) 2 ](PF 6 ) 2 ( 4 ) have been successfully prepared and fully characterized by NMR, ESI-MS spectroscopy, and X-ray diffraction analysis. The nickel complexes reveal a square-planar structure with two carbene ligands and benzimidazole groups at the cis configuration. The nickel complex 3b has been proved to be a highly efficient catalyst for Friedel–Crafts alkylation of indoles with β -nitrostyrenes at room temperature in moderate-to-excellent yields. The crystal packing structure of 4 shows that double-stranded 1D supramolecular chains are formed by inter-chain benzimidazole rings and pyridine rings face-to-face π - π stacking interactions.
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