Rubber elasticity transition of poly(silamine) induced by ionic interactions

Yukio Nagasaki,Kenji Kazama,Eiichi Honzawa,Masao Kato,Kazunori Kataoka,Teiji Tsuruta

Rubber elasticity transition of poly(silamine) induced by ionic interactions

1995

Yukio Nagasaki
Kenji Kazama
Eiichi Honzawa
Masao Kato
Kazunori Kataoka
Teiji Tsuruta

It is shown that the rubber elastic transition of poly(silamine) [NEtCH 2 CH 2 NEtCH 2 CH 2 SiMe 2 ] n is induced by the anion bindings along with the protonation. Especially, the change in the T g was more than 160 deg by the sulfuric acid protonation

Keywords:

Natural rubber
Photochemistry
Protonation
Ionic bonding
Rubber elasticity
Ion
Counterion
Polyelectrolyte
Organic chemistry
Inorganic chemistry
Glass transition
Chemistry
Acid–base titration

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