Atomic Force Microscopy of Electrochemical Nanoelectrodes

Nanometer-sized electrodes have recently been used to investigate important chemical and biological systems on the nanoscale. Although nanoelectrodes offer a number of advantages over macroscopic electrochemical probes, visualization of their surfaces remains challenging. Thus, the interpretation of the electrochemical response relies on assumptions about the electrode shape and size prior to the experiment and the changes induced by surface reactions (e.g., electrodeposition). In this paper, we present first AFM images of nanoelectrodes, which provide detailed and unambiguous information about the electrode geometry. The effects of polishing and cleaning nanoelectrodes are investigated, and AFM results are compared to those obtained by voltammetry and SEM. In situ AFM is potentially useful for monitoring surface reactions at nanoelectrodes.