Catalytic Hydrogenations with Cationic Heteroleptic Copper(I)/N-Heterocyclic Carbene Complexes
2019
A new heteroleptic cationic copper(I) complex bearing two N-heterocyclic carbene (NHC) ligands has been prepared. In situ, a Cu–O bond can be generated which enables the complex to catalytically activate H 2 . The resulting complex shows activity in catalytic chemo- and stereoselective alkyne semihydrogenations as well as conjugate reductions of enones.
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