A Complete Study of the ν3 Band and Associated Hot Bands of CICN
1993
Abstract The infrared spectra of the ν 3 band of ClCN have been measured with a resolution of 0.0026 cm −1 using a Fourier transform spectrometer. Eight bands of 35 Cl 12 CN, five bands of 37 Cl 12 CN, and one band of 35 Cl 13 CN have been analyzed to obtain accurate bands origins and rotational constants. The accuracy of the calculated band origins is better than 0.0005 cm −1 . A first determination of quartic and sextic vibrational constants is proposed.
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