New Molecular Conductors Based on Metal Complex Anions

Abstract The preparation and electrical conduction properties of [TTF]3[Au(dmit)2]2, [TMTSF]3[Au(dmit)2]2 and [BEDT-TTF][Au(dmit)2] are described. The electrical conduction properties of the products obtained by the electrocrystallisation of [TEA]2[Ni(dmid)2] in the presence of a large excess of Group 1 cations are described and compared with the corresponding products obtained using [TBA]2[Ni(dmit)2].