Ultrafast Atomic Diffusion Inducing a Reversible (2 root 3x2 root 3)R30 degrees (root 3x root 3)R30 degrees Transition on Sn/Si(111) : B
2015
Dynamical phase transitions are a challenge to identify experimentally and describe theoretically. Here, we study a new reconstruction of Sn on silicon and observe a reversible transition where the surface unit cell divides its area by a factor of 4 at 250 degrees C. This phase transition is explained by the 24-fold degeneracy of the ground state and a novel diffusive mechanism, where four Sn atoms arranged in a snakelike cluster wiggle at the surface exploring collectively the different quantum mechanical ground states.
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