Wetting Kinetics and Microstructure Analysis of BNi2 Filler Metal over Selective Laser Melted Ti-6Al-4V Substrate.

The wetting kinetics of nickel-based filler metal (BNi2) over selective laser-melted Ti-6Al-4V (SLMed TC4) titanium alloy in a protective argon atmosphere is experimentally investigated using a real-time in situ hot stage equipped with an optical microscope. The spreading processes at different temperatures are similar, and the overall wetting/spreading process can be roughly divided into three stages: (i) an initial stage, (ii) a rapid spreading stage, and (iii) an asymptotic stage. Moreover, the wetting kinetics of the BNi2/SLMed TC4 system can be expressed by empirical power exponential function Rn~t with n = ~1. In the process of spreading, Ti-based solid solution (Ti(ss)) and intermetallic compound (Ti2Ni and TiB2) were formed at the interface within the reaction domain, and the phase transition of α’ martensitic to α-Ti and β-Ti also took place. The influence of elevated temperature on the spreading and wetting kinetics of the BNi2/SLMed TC4 system was studied, and the results show that the increase of temperature has a slightly promoting effect on the spreading, but a limited impact on the value of n. In addition, the spreading and wetting kinetics of BNi2/SLMed TC4 system are similar to those of BNi2 on conventional forged TC4 substrate.