Plates soaking prior formation and its influence on positive active material phase composition and battery performance

Abstract In the present work, we studied the behaviour of 3BS and lead oxide paste as a function of soaking time in two sulfuric acid solutions respectively with 1.05 and 1.20 g cm −3 specific gravity. The study was based on X-ray diffraction analysis (XRD), thermogravimetry (TG), differential scanning calorimetry (DSC) and chemical analysis. The results showed that during plates soaking, 3BS and PbO are converted to monobasic lead sulphate (1BS) and lead sulphate (PbSO 4 ). During plate formation in 1.05 s.g. H 2 SO 4 solution, these compounds are oxidized to PbO 2 , the XRD patterns showed that the longer is the time of plates soaking prior formation the lower is α-PbO 2 content in positive active material. On forming, PbSO 4 crystals convert to β-PbO 2 whereas α-PbO 2 is a result of 3BS oxidation. The capacity and cycle life of PAM decrease with soaking time, the concentration of the H 2 SO 4 solution during soaking exerts stronger influence than the duration of soaking.