Physical properties of polycrystalline Sm 2 PdGe 6 and Sm 2 PtGe 6

The compounds Sm2TGe6 (T = Pd, Pt,) were synthesized and characterized by x-ray diffraction, magnetization, electrical resistivity, thermoelectric power, and specific heat measurements performed in the temperature range 2–300 K. Additional resistivity and thermoelectric power measurements performed down to 0.35 K have not indicated superconductivity. These compounds crystallize in the orthorhombic structure of Ce2NiGe6 type and order antiferromagnetically at 23(1) and 30(1) K, respectively, showing localized magnetism of a Sm 3+ ion with a crystal field doublet level being the ground state. Below TN, the electrical resistivity, the thermoelectric power, and the specific heat are dominated by electron–magnon scattering with an antiferromagnetic spin-wave spectrum typical of anisotropic antiferromagnetic systems. The thermoelectric power, S, achieves medium positive values at high temperatures, indicating a hole domination in electrical transport in both samples. At low temperatures, S changes its sign and becomes negative. At about 10 K a small negative maximum in S(T ) occurs for both studied compounds. All the measurements carried out point to well-localized 4f-electrons in these two compounds, being strongly influenced by the crystal-electric-field effect with a significant admixture of two J -multiplets (5/ 2a nd 7/2), typical for Sm-containing compounds. (Some figures in this article are in colour only in the electronic version)