The Barbier Reaction of 1-(Chloromethyl)benzotriazole with Aldehydes and Ketones Mediated by Samarium Diiodide.

Zhi-Zhen Huang,Hongwei Jin,De‐Hui Duan,Xian Huang

The Barbier Reaction of 1-(Chloromethyl)benzotriazole with Aldehydes and Ketones Mediated by Samarium Diiodide.

2000

Zhi-Zhen Huang
Hongwei Jin
De‐Hui Duan
Xian Huang

1-(Chloromethyl)benzotriazole can smoothly undergo the SmI2–Barbier reaction with aldehydes and ketones to give 1-β-(hydroxyalkyl)benzotriazoles under very mild conditions.

Keywords:

Barbier reaction
Samarium diiodide
Benzotriazole
Chemistry
Organic chemistry
triazole derivatives

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