Electronic processes of conjugated polymers in semiconductor device structures

Abstract We report progress in the processing and application of poly(phenylene vinylene), PPV, as the emissive layer in electroluminescent diodes, LEDs. Photoluminescence efficiencies above 60% for solid films of PPV are now achieved, and single-layer EL diodes achieve luminous efficiencies above 2 Lumens/W and peak brightnesses up to 90,000 cd/m 2 . We demonstrate that PPV of this type can show stimulated emission in sub-picosecond pump-probe experiments, and can be used as the active lasing medium when incorporated in suitable microcavity structures.