Kinetic Study of Ni and NiO Reactions Pertinent to the Earth’s Upper Atmosphere

Nickel atoms are injected into the Earth’s mesosphere by meteoric ablation, producing a Ni layer between 70 and 105 km in altitude. The subsequent reactions of Ni and NiO with atmospherically relevant species were studied using the time-resolved pulsed laser photolysis-laser-induced fluorescence technique, combined with electronic structure calculations and RRKM theory where appropriate. Results for bimolecular reactions (in cm3 molecule–1 s–1): k(Ni + O3, 293 K) = (6.5 ± 0.7) × 10–10; k(NiO + O3 → Ni + 2O2, 293 K) = (1.4 ± 0.5) × 10–10; k(NiO + O3 → NiO2 + O2, 293 K) = (2.5 ± 0.7) × 10–10; k(NiO + CO, 190–377 K) = (3.2 ± 0.6) × 10–11 (T/200)−0.19±0.05. For termolecular reactions (in cm6 molecule–2 s–1, uncertainty ± σ over the stated temperature range): log10(krec,0(Ni + O2 + N2, 190–455 K)) = −37.592 + 7.168log10(T) - 1.5650(log10(T))2, σ = 11%; log10(krec,0(NiO + O2 + N2, 293–380 K)) = −41.0913 + 10.1064log10(T) – 2.2610(log10(T))2, σ = 22%; and log10(krec,0(NiO + CO2 + N2, 191–375 K)) = −41.4265 + 10....