Palladium(II)/Copper Halide/Solvent Combination for Selective Intramolecular Domino Reactions of Indolecarboxylic Acid Allylamides: An Unprecedented Arylation/Esterification Sequence.

Gianluigi Broggini,Vincenzina Barbera,Egle M. Beccalli,Elena Borsini,Simona Galli,Giuseppe Lanza,Gaetano Zecchi

Palladium(II)/Copper Halide/Solvent Combination for Selective Intramolecular Domino Reactions of Indolecarboxylic Acid Allylamides: An Unprecedented Arylation/Esterification Sequence.

2012

Gianluigi Broggini
Vincenzina Barbera
Egle M. Beccalli
Elena Borsini
Simona Galli
Giuseppe Lanza
Gaetano Zecchi

Indolylallylamides (I) and (IX) undergo intramolecular oxidation reactions in the presence of PdCl2(MeCN)2 and CuCl2 to produce functionalized β-carbolinones (II).

Keywords:

Domino
Redox
Solvent
Copper
Palladium
Halide
Intramolecular force
Organic chemistry
Chemistry

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