Asymmetrical Electrowetting on Dielectrics Induced by Charge Transfer through an Oil/Water Interface

Electrowetting on dielectrics is a fascinating as well as a precise way in microfluid manipulation. As one of the controversial conclusions, charge trapping on the dielectric surface might be one of the causes which induces water contact angle saturation and forms one of the significant issues that bear on the applications of electrowetting on dielectrics. Recently, it was demonstrated that the contact angle saturation can be significantly reduced by employing an oil lubrication layer on the hydrophobic surface. In this work, we have investigated the influence of effects of an oil layer on the electrowetting behavior by dissolving a nonpolar oil-soluble dye in the oil phase. We monitored the contact angle of water drops with varying pH on an oil-lubricated hydrophobic insulator. Interestingly, we found asymmetry in the electrowetting curve. Several analysis methods were proceeded trying to explain this asymmetric electrowetting phenomenon. First and foremost, the electrochemical properties of dye were inv...