Laser-powered homogeneous pyrolysis of triisobutylgallane and tri-tert-butylgallane
1992
The gas-phase pyrolysis of tri-tert-butylgallane and triisobutylgallane has been studied using infrared laser-powered homogeneous pyrolysis. Identification of products by infrared and NMR spectroscopies confirmed that the predominant reaction pathway is β-hydride elimination in both cases, but that the pyrolysis proceeds at a significantly lower temperature than that of triethylgallium.
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