A study on the photoluminescence properties of electrospray deposited amorphous and crystalline nanostructured ZnO thin films

AbstractTransparent amorphous and crystalline nanostructured zinc oxide (ZnO) thin films were prepared by electrospray deposition technique on aglass substrateat250 8Cusingzincnitrateandammoniaastheprecursors.Thestructuralmorphologyandopticalpropertiesofthethinfilmswereevaluated and also the effect of formation rate of basic generating species on the morphology of the thin films was discussed. Optical studiesindicated that all of the thin films have a near band edge emission at 374 nm and a band gap of 3.32 eV. In addition, the films have an emission at393 nm corresponding to ultra violet (UV) transmittance. However, the amorphous thin films have oxygen trap peak at 430 nm and two greentransmittance peaks at 485 nm and 530 nm which are absent in the 0.1 molar nanostructured sample. The crystallite size of the thin films whichcalculated from XRD patterns via Debye–Scherrer’s formula was around 30 nm.# 2011 Elsevier Ltd and Techna Group S.r.l. All rights reserved. Keywords: D. ZnO; Thin film; Electrospray deposition; Optical property