Synthesis, crystal structure and DFT study of a dinuclear CuI complex with (E)-2-benzylidene- N-methylhydrazinecarbothioamide: Role of halogen-hydrogen bonds in copper-copper bridge bonding

An equimolar reaction of copper(I) chloride with the (E)-2-benzylidene-N-methylhydrazinecarbothioamide (btscH-N1HMe) thio-ligand in acetonitrile followed by the addition of one equivalent of triphe...