Double Axially Chiral Bisphosphorylimides Catalyzed Highly Enantioselective and Efficient Friedel—Crafts Reaction of Indoles with Imines.

Kun Wu,Yi-Jun Jiang,Yan-Sen Fan,Di Sha,Suoqin Zhang

Double Axially Chiral Bisphosphorylimides Catalyzed Highly Enantioselective and Efficient Friedel—Crafts Reaction of Indoles with Imines.

2013

Kun Wu
Yi-Jun Jiang
Yan-Sen Fan
Di Sha
Suoqin Zhang

BINOL and VAPOL-derived double axially chiral bisphosphorylimide catalysts enable the atom-economical and highly enantioselective Friedel—Crafts reaction between indoles and N-tosylimines with a low catalyst loading.

Keywords:

Axial symmetry
Enantioselective synthesis
Chirality (chemistry)
Friedel–Crafts reaction
Catalysis
Organic chemistry
Chemistry

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