Preparation and catalytic activities of LaFeO3 and Fe2O3 for HMX thermal decomposition.

Abstract Perovskite-type LaFeO 3 and α - Fe 2 O 3 with high specific surface areas were directly prepared with appropriate stearic acid–nitrates ratios by a novel stearic acid solution combustion method. The obtained powders were characterized by XRD, FT-IR and XPS techniques. The catalytic activities of perovskite-type LaFeO 3 and α-Fe 2 O 3 for the thermal decomposition of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) were investigated by TG and TG–EGA techniques. The experimental results show that the catalytic activity of perovskite-type LaFeO 3 was much higher than that of α - Fe 2 O 3 because of higher concentration of surface-adsorbed oxygen (O ad ) and hydroxyl of LaFeO 3 . The study points out a potential way to develop new and more active perovskite-type catalysts for the HMX thermal decomposition.