Metallorganische Lewis-Säuren: XLIV. Rheniooxy(organyl)carben-Komplexe von Chrom, Molybdän und Wolfram☆
1992
Abstract The addition of the strong organometallic Lewis acid Re(CO) 5 + (as (OC) 5 ReFBF 3 ) to anionic acyl complexes L(OC) 4 MC(R)O − (M Cr, W; L CO, PPh 3 ; R Me, Ph, Fc ferrocenyl) and to the anions from ethoxy acetylene and the hexacarbonyls of chromium, molybdenum and tungsten gives the title complexes L(OC) 4 MC(R)ORe(CO) 5 ( 1 ) and (OC) 5 M CC(OEt)C ORe(CO) 5 ( 2 ), respectively. The structure of 2a (M Cr) has been determined by X-ray diffraction.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
62
References
14
Citations
NaN
KQI