Reductive cleavage as a route to carbohydrate enolates. Applications to the synthesis of C-linked disaccharides
1995
The carbohydrate-derived α-bromo ketones 4 and 5undergo reductive cleavage using either Zn–Cu or CeCl3–Nal and the resulting enolates are trapped by carbohydrate-based aldehydes 6, 7 and 14 to give C-disaccharide derivatives.
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