Crystal Structure of a Diazenido-Dithiocarbamate Complex of Technetium, [Tc(NNC6H4Cl)((CH3)2NCS2)2(PPh3)]

The title complex [Tc(NNC₆H₄Cl)((CH₃)₂NCS₂)₂(PPh₃)] crystallizes in the monoclinic space group C 2/c with a = 3305.6(2), b = 1155.3(1), c = 2545.1(2) pm and β = 131.065(5)°. The final R value is 0.044.