Method for preparing lead chloride and calcium sulfate from lead plasters of waste lead accumulators by wet process

The invention discloses a method for preparing lead chloride and calcium sulfate from lead plasters of waste lead accumulators by a wet process. The lead plasters of the waste lead accumulators are taken as a raw material, and the method comprises the following steps of: leaching the lead plasters in an HCl-NaCl system; cooling the leach solution to separate out crystals; and separating, washing and drying. The method is characterized in that: a sulfur resource is recovered from cooling crystallization filtrate, and the cooling crystallization filtrate is in a closed cycle; the cooling crystallization filtrate is added with calcium chloride to form a calcium sulfate precipitate; the calcium sulfate precipitate is separated, washed and dried to form a calcium sulfate product; and the filtrate is used for preparing saturated NaCl solution which returns to the leaching process. Through the method, the lead chloride is obtained, and the industrial gypsum with the purity of over 97 percent is also obtained, so the sulfur resource is recycled, the cooling crystallization filtrate is circularly used, the lead recovery rate is over 96 percent after four times of circulation, and the waste of the lead resource and the lead pollution are avoided.