Accessing Nitrosocarbonyl Compounds with Temporal and Spatial Control via the Photoredox Oxidation of N-Substituted Hydroxylamines.

Abstract Photoredox catalysis is employed to generate highly reactive acylnitroso species from hydroxamic acid derivatives. The conditions are shown to be comparable to a previously developed transition metal aerobic oxidation and are amenable to a range of transformations including Diels–Alder and ene reactions. This unique application of such an approach gives access to temporal and spatial control in nitroso chemistry.