High-performance piezoelectric nanogenerators composed of formamidinium lead halide perovskite nanoparticles and poly(vinylidene fluoride)
2017
Abstract Formamidinium lead halide perovskite nanoparticles (FAPbBr 3 NPs), because of their prominent piezoelectric properties, have drawn increasing attention in the fields of piezoelectric applications. Remarkable enhancement of piezoelectric power output is achieved from a piezoelectric composite nanogenerator by combining the FAPbBr 3 NPs with poly(vinylidene fluoride) (PVDF) polymer. The FAPbBr 3 NPs @ PVDF composite based piezoelectric nanogenerators show the highest outstanding outputs with voltage of 30 V and current density of 6.2 μA cm −2 for organic-inorganic lead halide perovskite material based devices. The improved performance can be ascribed to the using of PVDF, piezoelectric polymer as matrix, as well as the homogeneous distribution of FAPbBr 3 NPs with enhanced stress on piezoelectric nanoparticles. The alternating energy generated from the nanogenerator can be utilized to charge a capacitor through a bridge rectifier and light up a commercial light-emitting diode (LED). Our obtained results open the feasibility of organic-inorganic lead halide perovskite materials for the design and development of high-efficiency energy harvesting applications.
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