Photochemistry of 1,3-dioxolane radical cations in sulfur hexafluoride and freonic matrices at 77 K

The elementary stages and efficiency of the photochemical reactions of 1,3-dioxolane radical cations in various low-temperature matrices (sulfur hexafluoride, Freon-11, Freon-113) were determined. The matrix effects in the photochemical processes were observed experimentally. Possible reasons for these effects are discussed.