Enhancing the thermal insulating properties of lanthanum zirconate porous ceramics via pore structure tailoring

Abstract The potentially useful role of lanthanum zirconate (La2Zr2O7, LZO) porous bulk ceramics has been rarely explored thus far, much less the optimisation of its pore structure. In this study, LZO porous ceramics were successfully fabricated using a tert-butyl alcohol (TBA)-based gelcasting method, and the pore structures were tailored by varying the initial solid loading of the slurry. The as-prepared ceramics exhibited an interconnected pore structure with high porosity (67.9%-84.2%), low thermal conductivity (0.083-0.207 W/(m·K)), and relatively high compressive strength (1.56-7.89 MPa). The LZO porous ceramics with porosity of 84.2% showed thermal conductivity as low as 0.083 W/(m·K) at room temperature and 0.141 W/(m·K) at 1200 °C, which is much lower than the counterparts fabricated from particle-stabilized foams owing to its unique pore structure with a smaller size, exhibiting better thermal insulating performance.