Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp2)–H Bond Functionalization

A Cp*Rh(III)-dithiophosphate cofactor with “latent” catalytic activity was developed to construct an artificial metalloenzyme representing a new type of biohybrid catalyst which is capable of promo...