Vergelijkende PM10-metingen in Nederland. deel A: laboratoriumexperimenten
2002
Automatic FAG 62I-N beta-dust monitors have been used in the National Air
Quality Monitoring Network to measure PM10 (particles smaller than 10 um
aerodynamic diameter) in the Netherlands. In comparing the 5-method with
the European reference method (EN12341) for PM10, this automatic
beta-method was found to underestimate the PM10 levels observed using the
reference method by about 25%. Laboratory research was then carried out
to explore the causes. These laboratory experiments focussed on the
influence of moisture on the response of the monitor, and on the
influence of the inlet heating on both the volatile ammonium nitrate
aerosol and the less volatile ammonium sulphate aerosol. Humidity will
only slightly increase the concentrations measured by the beta-dust
monitor. At very high humidities (RH over 80%), positive offsetting
(overestimation) of the dust concentration of up to about 3-4 ug/m3 was
observed when compared to the reference method. Thus humidity can not
explain the aforementioned difference of 25% at commonly encountered PM10
levels. The inlet heating of the beta-dust monitor definitively does
evaporate volatile ammonium nitrate aerosol. At the maximum set
temperature (80 degrees Celcius) of the inlet heating element of the FAG
62I-N beta-dust monitor, ammonium nitrate will be completely evaporated,
and so no ammonium nitrate is measured. At the standard setting of 50
degrees Celcius the ammonium nitrate will partly evaporate, i.e. only
part of the ammonium nitrate is measured. In contrast, the TEOM (Tapered
Element Oscillation Microbalance) evaporates all the ammonium nitrate.
The heating efficiencies of the monitors are clearly different. For this
reason they can not be compared when volatile aerosol is present. The
less volatile ammonium sulphate aerosol does not experience any influence
of inlet heating, so the methods of measurement are comparable in this
case.
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