Synthesis and luminescence properties of CaSnO3:Bi3+ blue phosphor and the emission improvement by Li+ ion

: CaSnO3 :Bi3+ blue-emitting phosphor was synthesized using a high-temperature solid-state reaction method in air. The crystal structures and luminescence properties were investigated. A broad emission band peaking at ~448 nm upon excitation at 262 and 308 nm was observed in the range 330-680 nm at room temperature due to 3 P1  → 1 S0 transition of the Bi3+ ion. The chromaticity coordinate was (0.1786, 0.1665). The optimal Bi3+ ion concentration was ~0.6 mol% in CaSnO3 :Bi3+ phosphor. The emission spectrum of CaSnO3 :Bi3+ phosphor showed a blue-shift with increasing temperature from 50 to 300 K due to the influence of temperature on the electron transition of the Bi3+ ion. The emission intensity of CaSnO3 :Bi3+ phosphor may be increased ~1.45 times by co-doping Li+ ions as a charge compensator and fluxing agent. The luminescence mechanism is explained by a configurational coordinate diagram of Bi3+ ion in CaSnO3 :Bi3+ phosphor.