Exploiting Feedstock Diversity To Tune the Chemical and Tribological Properties of Lignin-Inspired Polymer Coatings
2018
Biobased polymers present an immense opportunity to design and manufacture new coating materials largely as a result of their feedstock diversity and inherent functionality, yet unraveling the key structure/property relationships inherent in these environmentally friendly systems remains a considerable challenge. A major focus of this work was to develop functional group–property design rules for a representative library of lignin-inspired polymers. Of particular interest were the polymers’ solubilities, surface energies, and friction coefficients because of their relevance to coatings applications. The structural diversity of our bioinspired library, consisting of various polymers generated from methacrylate-functionalized lignin pyrolysis products, arose from the differing moieties at the para and ortho positions on the polymer repeat units relative to the methacrylate backbone. Polymer compatibilities with organic solvents studied herein increased with greater aliphatic content in the para functionalit...
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