Cp2TiCl2-CATALYZED PHOTOREDOX ALLYLATION OF ALDEHYDES WITH VISIBLE LIGHT

Andrea Gualandi,Francesco Calogero,Martino Mazzarini,Simone Guazzi,Andrea Fermi,Giacomo Bergamini,Pier Giorgio Cozzi

Cp2TiCl2-CATALYZED PHOTOREDOX ALLYLATION OF ALDEHYDES WITH VISIBLE LIGHT

2020

Andrea Gualandi
Francesco Calogero
Martino Mazzarini
Simone Guazzi
Andrea Fermi
Giacomo Bergamini
Pier Giorgio Cozzi

A Barbier-type Cp2TiCl2-mediated (10 mol%) photoredox allylation of aldehydes under irradiation with visible light (blue LEDs, 450 nm) and in the presence of an organic dye (3DPAFIPN, 5 mol%) with allylbromides is described.

Keywords:

Irradiation
Light-emitting diode
Catalysis
Photochemistry
organic dye
Chemistry
Visible spectrum
Photoredox catalysis
Aldehyde
Titanium

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