Heterolytic C–O cleavage in arylethers activated by [Fe(η5-C5H5)]+

Françoise Moulines,Laurent Djakovitch,Marie-Hélène Delville-Desbois,Francis Robert,Pierre Gouzerh,Didier Astruc

Heterolytic C–O cleavage in arylethers activated by [Fe(η5-C5H5)]+

1995

Françoise Moulines
Laurent Djakovitch
Marie-Hélène Delville-Desbois
Francis Robert
Pierre Gouzerh
Didier Astruc

The C–O bond of Fe(η5-C5H5)+ complexes of aryl ethers is cleaved smoothly by reaction of ButOK in THF or KOH in DME, yielding π-phenate complexes; transetherification can also be achieved in situ at room temperature.

Keywords:

Aryl
Inorganic chemistry
Heterolysis
Substitution reaction
Cleavage (embryo)
Chemistry
Photochemistry
Organic chemistry
In situ

Correction
Source
Cite
Save
Machine Reading By IdeaReader

References

Citations