Theoretical Study of Molecular Hydrogen Adsorption in Mg-Exchanged Chabazite
2007
An enthalpy of adsorption of ca. −10 kJ/mol was theoretically predicted for the interaction of molecular hydrogen with Mg-exchanged low silica chabazite (Si/Al = 5/1), which is significantly higher than the theoretical prediction for alkali-metal-exchanged chabazites (−3.0/−7.0 kJ/mol) and in acceptable agreement with a recent experimental finding of −17.5 kJ/mol obtained for a different zeolite, that is, (Mg,Na)−Y.
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