Characterization of aerosol optical properties using multiple clustering techniques over Zanjan, Iran, during 2010–2013

Discrimination of aerosol types is very important, because different aerosols are created from diverse sources having different chemical, physical, and optical properties. In the present study, we have analyzed the seasonal classification of aerosol types by multiple clustering techniques, using AERosol Robotic NETwork (AERONET) data during 2010–2013 over Zanjan, Iran. We found that aerosol optical depth (AOD) showed pronounced seasonal variations of a summer high and winter low. Conversely, the values of the Angstrom exponent (AE) in winter and fall were higher than in spring and summer, which confirmed the presence of fine particles, while the low value of AE in the summer and spring represented the existence of coarse particles. Single Scattering Albedo (SSA) variations revealed the presence of scattering aerosols like dust in spring, summer, and fall while the dominance of absorbing-type aerosols in winter were also observed. The influence of local anthropogenic activities has caused a higher concentration of fine aerosols, and a higher fine mode fraction (FMF) of AOD in winter was recorded. Classification of aerosol types was carried out by analyzing different aerosol properties such as AOD versus AE, extinction Angstrom exponent (EAE) versus SSA, EAE versus absorption Angstrom exponent (AAE), FMF AOD versus EAE, and SSA versus FMF AOD. The analysis revealed the presence of dust and polluted dust in spring, summer, and fall in the atmosphere of Zanjan. Urban/industrial aerosols were available in all seasons, especially in fall and winter. The mixed aerosols existed in all seasons over the study location; however, no biomass burning aerosols were found. The Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) aerosol subtype profiles showed the dominance of dust and polluted dust in spring and summer. However, the presence of polluted dust and industrial smoke during fall and winter were also noted over the study site.