Spontaneous Formation of Interwoven Porous Channels in Hard-Wood-Based Hard-Carbon for High-Performance Anodes in Potassium-Ion Batteries
2017
For the first time we report that hard-wood (oak) can spontaneously create interconnected channels of μm to nm in diameter during carbonization at an optimized temperature (1100°C). These microstructural features have never been found in other hard-carbons without the use of additives. When compared with sucrose-based hard-carbon (SHC), oak-based hard-carbon (OHC) shows much higher charge-storage capability (ca. 223 vs. 112 mAhg−1 at 20 mAg−1) and excellent stability (fading rate of 0.04 vs. 0.08%cycle−1) as an anode in potassium-ion batteries. The high performance of OHC mainly results from interwoven nanoporous channels, which lead to facile charge transfer and fast K+-diffusion.
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