Selective Metalation of 4,6-DibromoresorcinolDimethyl Ether with LiTMP

George A. Kraus,Insik Jeon,John Mengwasser,Aaron C. West,Theresa L. Windus

Selective Metalation of 4,6-DibromoresorcinolDimethyl Ether with LiTMP

2010

George A. Kraus
Insik Jeon
John Mengwasser
Aaron C. West
Theresa L. Windus

4,6-Dibromoresorcinol dimethyl ether was selectively metalated at C-5 with lithium tetramethylpiperidide (LiTMP). A rationale for the selective metalation is proposed.

Keywords:

Dimethyl ether
Alkylation
Photochemistry
Lithium tetramethylpiperidide
Metalation
Ether
Regioselectivity
Organic chemistry
Inorganic chemistry
Chemistry

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