Electrochemical Reduction-assisted in situ Fabrication of Graphene/Au Nanoparticles@polyoxometalate Nanohybrids film: High Performance Electrochemical Detection for Uric Acid.
2020
Nanohybrid
films had attracted much attention owning to the enhancement
of catalytic activity. However, the fabrication time took hours to
days, no matter if it was the preparation of nanohybrids or the assembly
process. Furthermore, the catalytic efficiency of the nanohybrid film
still remained to improve. In this paper, a reduced graphene oxide
(rGO)/gold nanoparticles (Au NPs)@polyoxometalate (POM) nanohybrid
film was successfully fabricated by combining electrodeposition and
electrochemical reduction in situ processes. The
assembly process involving no organic or polymer linker molecules
[except for a precursor poly(ethylenimine) (PEI) coating for indium
tin oxide (ITO)] can be completed within 1 h. The reduced POM K6[P2W18O62]·19H2O (P2W18) was employed as reducing agents and
bridging molecules for rGO and Au nanoparticles and the encapsulating
molecules for the Au nanoparticles. The most interesting one is the
{rGO/Au@P2W18} modified electrode loading only
the monolayer catalyst of Au@P2W18 and exhibiting
comparable, even better electrochemical detection performance toward
uric acid than other sensors with three to eight layers of the catalyst.
The amperometric detection displayed a great sensitivity, lower detection
limit, wide linear range, good long-time stability, superior selectivity,
and reproducibility. The enhanced catalytic property may attribute
to the improved conductivity of the film without organic or polymer
linker molecules (except for a precursor PEI coating) and the electron
transfer in the process of film fabrication.
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