Preparation of c-axis-oriented zinc-oxide thin films and the study of their microstructure and optical properties

Abstract c -axis-oriented zinc-oxide (ZnO) thin films were prepared on microscope glass substrates by sol–gel deposition. A homogeneous and stable solution was prepared by dissolving zinc-acetate 2-hydrate (ZnAc) in 2-propanol and diethanolamine. Crystalline ZnO thin films were obtained following an annealing process at temperatures between 450°C and 550°C for 1 h. Increasing annealing temperature increased the grain size and the c -axis orientation. The X-ray diffraction analysis revealed single-phase ZnO with hexagonal zincite structure. The absorption edge analysis revealed that the optical band-gap energy for the films were between 3.26 and 3.28 eV and electronic transition was direct transition type.