Synthesis and characteristics of novel fluorescence dyes based on chromeno[4,3,2-de][1,6]naphthyridine framework
2013
Abstract A series of entirely new framework chromeno[4,3,2- de ][1,6]naphthyridine derivatives containing carbazole groups have been carefully designed and prepared. The relationship of photoluminescence property and structure of these compounds was systematically investigated via UV–vis, fluorescence and electrochemical analyzer. The HOMO and LUMO distributions of these compounds were calculated by density functional theory (DFT) (B3LYP; 6-31G ∗ ) method. These compounds exhibited high fluorescence quantum yields, desirable HOMO levels and high thermal stability, indicating that the combination of chromeno[4,3,2- de ][1,6]naphthyridine and carbazole could be an efficient means to enhance hole-transporting ability and fluorescent quantum yield.
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